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Statistical Mechanics of Phase Transitions and Kinetics
Edward Timoshenko
This course is devoted to advances of Statistical Mechanics beyond the ideal equilibrium systems. We proceed from the systematic calculation of corrections to the ideal gas law and the van der Waals theory. Next, two-phase coexistence is studied and the Maxwell rule is obtained. The Flory-Huggins theory is derived for polymer solutions. We discuss the generic aspects of phase transitions, phase diagrams, metastable states and applications to chemical reactions.
For molecular solutions we derive the Dalton’s, Raoult’s and Henry’s laws, as well as the Van’t-Hoff’s law. Concepts of the non-equilibrium Statistical Mechanics and the Kinetics of phase transitions are overviewed.
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